アロフェンの高分解能電子顕微鏡写真

アロフェンの化学構造（中央の空隙は、球壁の穴部）

ナノボールアロフェンの構造

                   アロフェン中空球壁の化学構造

ナノチューブ・イモゴライトの化学構造

アロフェン及びイモゴライトに関するいくつかの登録特許

特許第3378515号 イモゴライトの製造方法

特許第3011213号 アロフェンの製造方法

特許第2845985号 懸濁液耕栽培法

特許第2577709号 鉄イオン徐放出性のコンクリート構築物

アロフェン及びイモゴライトに関するいくつかの論文

K. Wada and T. Henmi (1972) CHARACTERIZATION OF MICROPORES OF IMOGOLITE BY MEA SURING OF QUATERNARY AMMONIUM CHLORIDES AND WATER, Clay Sci., Vol.4, 127-136.

K. Wada,T.Henmi,N.Yoshinaga and S.H. Patterson (1972)IMOGOLITE AND ALLOPHANE FORMED IN SAPROLITE OF BASALT ON MAUI, HAWAII, Clays & Clay Miner., Vol.20, 375-380.

T. Henmi and K. Wada (1974) SURFACE ACIDITY OF IMOGOLITE AND ALLOPHANE, Clay Miner., Vol.11, 231-245.

T. Henmi and K. Wada (1976) MORPHOLOGY AND COMPOSITION OF ALLOPHANE, Am. Miner., Vol. 61, 379-390.

K. Wada and T. Henmi (1976) SURFACE ACIDITY OF IMOGOLITE AND ALLOPHANE: A REPLY, Clay Miner., Vol.11, 335-337.

T. Henmi (1977) THE DEPENDENCE OF SURFACE ACIDITY ON CHEMICAL COMPOSITION (SiO２ /Al２O３ MOLAR RATIO) OF ALLOPHANE, Clay Miner., Vol.12, 356-358.

T. Henmi (1979) THE OCCURRENCE OF ALLOPHANE IN A STREAM-DEPOSIT FROM EHIME-PREF ECTURE, JAPAN, Clay Miner., Vol.14, 333-338.

T. Henmi and R.L. Parfitt (1980) LAMINAR OPALINE SILICA FROM SOME VOLCANIC ASH SO ILS IN NEW ZEALAND, Clays & Clay Miner., Vol.28, 57-60.

T. Henmi (1980) EFFECT OF SiO２/Al２O３ RATIO ON THERMAL REACTIONS OF ALLOPHANE, Clays & Clay Miner., Vol.28, 92-96.

R.L. Parfitt and T. Henmi (1980) STRUCTURE OF SOME ALLOPHANES FROM NEW ZEALAND, Clays & Clay Miner., Vol.28, 285-294.

T. Henmi, N. Wells, C.W. Childs and R.L. Parfitt (1980) POORLY-ORDERED IRON-RICH PRECIPITATES FROM SPRINGS AND STREAMS ON ANDESITIC VOLCANOES, Geochim. Cosmochim. Acta, Vol.41, 365-372.

R.L. Parfitt, R.J. Furkert and T. Henmi (1980) IDENTIFICATION AND STRUCTURE OF TW O TYPES OF ALLOPHANE FROM VOLCANIC ASH SOILS AND TEPHRA, Clays & Clay Miner., Vol.28, 328-334.

K. Inoue, M. Yoshida and T. Henmi (1980) THE OCCURRENCE OF ALLOPHANE IN STREAM-DEPOSITS FROM SHISHIGAHANA AT THE NORTHERN FOOT OF MT. CHOKAI, JAPAN, Clay Sci., Vol.5, 267-276.

T. Henmi and N. Yoshinaga (1981) ALTERATION OF IMOGOLITE BY DRY GRINDING, Clay Miner., Vol.16, 139-149.

T. Henmi, K. Tange, T. Minagawa and N. Yoshinaga (1981) EFFECT OF SiO２/Al２O３ RATI O ON THE THERMAL REACTIONS OF ALLOPHANE. II.INFRARED AND X-RAY POWDER DIFFRACTION DATA, Clays & Clay Miner., Vol.29, 124-128.

R.L. Parfitt and T. Henmi (1982) COMPARISON OF AN OXALATE-EXTRACTION METHOD AND AN INFRARED SPECTROSCOPIC METHOD FOR DETERMINING ALLOPHANE IN SOIL CLAYS, Soil Sci. Plant Nutr., Vol.28, 183-190.

逸見彰男、中井 信、楠香谷隆規、吉永長則 (1982) 火山灰土壌および風化浮石の粘土によるリンの吸着除去、愛媛大農学部紀要、第２７巻、１７−２４．

T. Henmi, M. Nakai, T. Seki and N. Yoshinaga (1983) STRUCTURAL CHANGES OF ALLOPHANES DURING DRY GRINDING: DEPENDENCE ON SiO２/Al２O３, Clay Miner., Vol.18, 101-107.

逸見彰男 (1983) 火山灰土壌粘土による河川および湖沼水中のリンの除去、環境改善技術の化学的手法研究報告（三枝武夫編集）、８３−８７．

N. Yoshinaga, M. Nakai, T. Minagawa and T. Henmi (1984) FORMATION OF IMOGOLITE AN D ALLOPHANE IN SHATTERED SANDSTONE UNDERLYING BROWN FOREST SOIL, Soil Sci. Plant Nutr., Vol.30, 555-567.

T. Henmi and P.M. Huang (1985) REMOVAL OF PHOSPHORUS BY POORLY ORDERED CLAYS AS INFLUENCED BY HEATING AND GRINDING, Applied Clay Sci., Vol.1, 133-144.

T. Henmi (1985) IMPORTANCE OF CHEMICAL COMPOSITION (SiO２/Al２O３ RATIO) AS FACTOR AFFECTING PHYSICO-CHEMICAL PROPERTIES OF ALLOPHANES FROM WEATHERED VOLCANIC ASH AND PUMICE, 5th Meeting of European Clay Groups (Ed. J.Konta), 459-464.

T. Henmi and P.M. Huang (1986) EFFECT OF PHOSPHATE ANION ON THE FORMATION OF IMOGOLITE, Proc. 8th Int. Clay Conf., 173-179.

逸見彰男 (1986) "プロトイモゴライトアロフェン”について、ペドロジスト、 第３０巻、１６３−１６８．

逸見彰男 (1987) アロフェンのケイバン比と性状および構造との関係、粘土科学、 第２７巻、３２−４４．

逸見彰男 (1987) アロフェンのＳｉＯ４四面体の存在様式、日本土壌肥料学雑誌、第５９巻、２３７−２４１.　

H. Shimizu, T.Watanabe, T. Henmi, A. Masuda and H. Saito (1988) STUDIES ON ALLOPHANE AND IMOGOLITE BY HIGH-RESOLUTION SOLID-STATE ２９Si- and ２７Al-NMR AND ESR, Geochem. J., Vol. 22, 23-31.

逸見彰男 (1988) アロフェン中空球状粒子の球壁の化学構造、 土壌の物理性、第５６号、４７−５０.

逸見彰男 (1989) 非晶質ケイ酸アルミニウム類について、愛媛大学機器分析センター報告、第４号、１０−１７.　　

逸見彰男 (1991) 非晶質粘土研究の考え方と方法論、粘土科学、第３１巻、７５−８１．

松枝直人、逸見彰男 (1993) アロフェンのＳｉ／Ａｌ比と表面酸性強度との関係に関する分子 軌道論的考察、粘土科学、第３３巻、１０２−１０６．

S. Ozeki, Y. Masuda, Y. Nishimoto and T. Henmi (1994) WATER IN SPHERICAL, CYLINDRICAL AND SLITLIKE PORES, Surface Science and Catalysis, Vol. 87, 179-186.

Wu De-Yi, N. Matsue, T. Henmi and N. Yoshinaga (1992) :SURFACE ACIDITY OF PYROPHYLITE AND TALC, Clay Sci., Vol. 8, 367-379.

松枝直人、逸見彰男、吉永長則 (1992) 粘土研究の今後の展望−分子軌道法 の適用−、粘土科学、第３１巻、１９０−１９５．

Wu De-Yi, N. Matsue, T. Henmi and N. Yoshinaga (1993) ADSORPTION OF ACRYLONITORILE ON SOME SOILS AND MINERALS FROM AQUEOUS SOLUTIONS, Pedosphere, Vol. 3, 253-259.

松枝直人、呉徳意、逸見彰男、吉永長則 (1993) ”中性”層状ケイ酸塩粘土 鉱物の表面ルイス酸性−酸性部位と酸性発現機構−、粘土科学、第３３巻、 １４６−１５１．

逸見彰男*・松枝直人*・Johan, E.*：オルトケイ酸との反応によるSi/Al比の低いアロフェンの表面酸性変化．日本土壌肥料学雑誌，68(5):514-520. 1997

Johan, E.*, Matsue, N.* and Henmi, T.*： Phosphate adsorption on nano-ball allophane and its molecular orbital analysis. Clay Science, 10(3):259-270. 1997

逸見彰男*・松枝直人*：アロフェンとイモゴライトの分別生成−共存する陽イオンの影響と分子軌道法的機構解析−．日本土壌肥料学雑誌，69(2)：21−28．1998

Son, L. T.*, Matsue, N.* and Henmi, T.*: Boron adsorption on allophane with nano-ball morphology. Clay Science, 10(4):315−325. 1998

逸見彰男*・松枝直人*・レ タン サン*：フッ化物イオン処理によるアロフェンおよびイモゴライトの表面特性変化−表面酸性および陽イオン交換容量の増大と分子軌道法計算によるメカニズム解析．日本土壌肥料学雑誌，69(5)：470−476．1998

逸見幾代・松枝直人・逸見彰男：希薄硝酸水溶液処理によるアロフェンとイモゴライトの構造変化およびアルミニウムとケイ素の溶出．日本土壌肥料学雑誌，70(1):25-30．1999

Johan, E., Matsue, N. and Henmi, T.: New concepts for change in charge characteristics of allophane with phosphate adsorption. Clay Science, 10(6):457-468. 1999

Hanudin, E., Matsue, N. and Henmi, T.: Adsorption of some low molecular weight organic acids on nano-ball allophane. Clay Science, 11(1):57-72.1999

逸見彰男：アロフェンの化学特性と構造に関する研究．日本土壌肥料学雑誌，70(3):251-254．1999

E. A. Elhadi, N. Matsue and T. Henmi: Adsorption of Molybdate on Nano-ball Allophane, Clay Science, 11(2):189-204. 2000

N. Eric, N. Matsue and T. Henmi :Adsorption Mechanisms of Orthosilicic acid on Nano-ball Allophane, Clay Science, 11(2): 125-136. 2000

逸見幾代・松枝直人・逸見彰男：希薄酸水溶液処理によるアロフェンからのアルミニウムとケイ素の溶出に及ぼす酸種及び共存する陰イオンの影響．粘土科学，41(2):58-63．2001

A. M. Ghoneim, N. Matsue and T. Henmi: Zinc adsorption on Nano-ball Allophane with different Si/Al ratios, Clay Science, 11(4): 337-348. 2001

Lee, D. B., Matsue, N. and Henmi, T. : INFLUENCE OF NaOH CONCENTRATIONS DISSOLVED IN SEA WATER AND HYDROTHERMAL TEMPERATURES ON THE SYNTHESIS OF ARTIFICIAL ZEOLITE FROM COAL FLY ASH, Clay Sci., Vol. 11, 451-463 (2001)

 Hanudin, E., Matsue, N. and Henmi, T. : REACTION OF SOME SHORT-RANGE ORDERED ALUMINOSILICATES WITH SELECTED ORGANIC LIGANDS, Soil Mineral-Organic Matter-Microorganisms Interactions and Ecosystem Health (Eds. A. Violante, P. M. Huang, J.-M. Bolla and L. Gianfreda), Developments in Soil Science 28A, Elsevier, 319-332 (2002)

Ghoneim, A. M., Matsue, N. and Henmi, T. : ADSORPTION MECHANISM OF COPPER AND ZINC ON NANO-BALL ALLOPHANE, Clay Sci., Vol. 11, 615-624 (2002)

 Padilla, G. N., Matsue, N. and Henmi, T. : ADSORPTION OF SULFATE AND NITRATE ON NANO-BALL ALLOPHANE, Clay Sci., Vol. 11, 575-584 (2002)

Padilla, G. N., Matsue, N. and Henmi, T. : CHANGE IN SURFACE CHARGE PROPERTIES OF NANO-BALL ALLOPHANE AS INFLUENCED BY SULFATE ADSORPTION, Clay Sci. (in press)